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不同地区的工程纳米材料(TiO(2)、ZnO、Ag、CNT、Fullerenes)的模拟环境浓度。

Modeled environmental concentrations of engineered nanomaterials (TiO(2), ZnO, Ag, CNT, Fullerenes) for different regions.

机构信息

Empa, Swiss Federal Laboratories for Materials Testing and Research, Technology and Society Laboratory, CH-9014 St. Gallen, Switzerland.

出版信息

Environ Sci Technol. 2009 Dec 15;43(24):9216-22. doi: 10.1021/es9015553.

Abstract

Engineered nanomaterials (ENM) are already used in many products and consequently released into environmental compartments. In this study, we calculated predicted environmental concentrations (PEC) based on a probabilistic material flow analysis from a life-cycle perspective of ENM-containing products. We modeled nano-TiO(2), nano-ZnO, nano-Ag, carbon nanotubes (CNT), and fullerenes for the U.S., Europe and Switzerland. The environmental concentrations were calculated as probabilistic density functions and were compared to data from ecotoxicological studies. The simulated modes (most frequent values) range from 0.003 ng L(-1) (fullerenes) to 21 ng L(-1) (nano-TiO(2)) for surface waters and from 4 ng L(-1) (fullerenes) to 4 microg L(-1) (nano-TiO(2)) for sewage treatment effluents. For Europe and the U.S., the annual increase of ENMs on sludge-treated soil ranges from 1 ng kg(-1) for fullerenes to 89 microg kg(-1) for nano-TiO(2). The results of this study indicate that risks to aquatic organisms may currently emanate from nano-Ag, nano-TiO(2), and nano-ZnO in sewage treatment effluents for all considered regions and for nano-Ag in surface waters. For the other environmental compartments for which ecotoxicological data were available, no risks to organisms are presently expected.

摘要

工程纳米材料(ENM)已经在许多产品中得到应用,因此被释放到环境介质中。在本研究中,我们基于含有纳米材料产品的生命周期概率物质流分析,计算了预测环境浓度(PEC)。我们对纳米二氧化钛(TiO2)、纳米氧化锌(ZnO)、纳米银(Ag)、碳纳米管(CNT)和富勒烯(Fullerenes)进行了建模,分别针对美国、欧洲和瑞士。环境浓度以概率密度函数的形式进行计算,并与生态毒理学研究的数据进行了比较。模拟模式(最常见的值)范围从地表水中的 0.003ng/L(富勒烯)到 21ng/L(纳米 TiO2),污水处理厂废水中的 4ng/L(富勒烯)到 4μg/L(纳米 TiO2)。对于欧洲和美国,每年污泥处理土壤中纳米材料的增加量范围从富勒烯的 1ng/kg 到纳米 TiO2 的 89μg/kg。本研究结果表明,目前对水生生物的风险可能来自所有考虑地区污水处理厂中的纳米 Ag、纳米 TiO2 和纳米 ZnO,以及地表水中的纳米 Ag。对于其他有生态毒理学数据的环境介质,目前预计不会对生物造成风险。

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