Enantioselective iridium-catalyzed vinylogous Reformatsky-aldol reaction from the alcohol oxidation level: linear regioselectivity by way of carbon-bound enolates.
作者信息
Hassan Abbas, Zbieg Jason R, Krische Michael J
机构信息
University of Texas at Austin, Department of Chemistry and Biochemistry, 1 University Station-A5300, Austin, TX 78712-1167, USA.
出版信息
Angew Chem Int Ed Engl. 2011 Apr 4;50(15):3493-6. doi: 10.1002/anie.201100646. Epub 2011 Mar 4.
Abstract
摘要
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Enantioselective iridium-catalyzed vinylogous Reformatsky-aldol reaction from the alcohol oxidation level: linear regioselectivity by way of carbon-bound enolates.从醇氧化水平进行对映选择性铱催化的乙烯型Reformatsky-羟醛反应：通过碳连接的烯醇盐实现线性区域选择性。
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Adv Synth Catal. 2010 Oct 4;352(14-15):2416-2420. doi: 10.1002/adsc.201000599.
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