Rose T L, Robblee L S
Research Division, EIC Laboratories, Norwood, MA 02062.
IEEE Trans Biomed Eng. 1990 Nov;37(11):1118-20. doi: 10.1109/10.61038.
The charge injection limits of a Pt electrode using 0.2 ms charge balanced, biphasic current pulses ranged from 50 to 150 microC/cm2 geometric if the potential excursions of the electrode are kept below those at which H2 or O2 is produced. These charge densities are three to ten times smaller than the currently accepted value based on earlier experiments in which the reversible surface reactions were fully utilized and the pulse widths were longer.
如果将电极的电位偏移保持在产生H2或O2的电位之下,使用0.2毫秒电荷平衡双相电流脉冲时,铂电极的电荷注入极限在几何面积上为50至150微库仑/平方厘米。这些电荷密度比基于早期实验的当前公认值小三到十倍,早期实验中充分利用了可逆表面反应且脉冲宽度更长。