Álvarez Andrea, Bansode Atul, Urakawa Atsushi, Bavykina Anastasiya V, Wezendonk Tim A, Makkee Michiel, Gascon Jorge, Kapteijn Freek
Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology , Avinguda dels Països Catalans 16, 43007 Tarragona, Spain.
Catalysis Engineering, Chemical Engineering Department, Delft University of Technology , Van der Maasweg 9, 2629 HZ Delft, The Netherlands.
Chem Rev. 2017 Jul 26;117(14):9804-9838. doi: 10.1021/acs.chemrev.6b00816. Epub 2017 Jun 28.
The recent advances in the development of heterogeneous catalysts and processes for the direct hydrogenation of CO to formate/formic acid, methanol, and dimethyl ether are thoroughly reviewed, with special emphasis on thermodynamics and catalyst design considerations. After introducing the main motivation for the development of such processes, we first summarize the most important aspects of CO capture and green routes to produce H. Once the scene in terms of feedstocks is introduced, we carefully summarize the state of the art in the development of heterogeneous catalysts for these important hydrogenation reactions. Finally, in an attempt to give an order of magnitude regarding CO valorization, we critically assess economical aspects of the production of methanol and DME and outline future research and development directions.
本文全面综述了用于将CO直接加氢生成甲酸盐/甲酸、甲醇和二甲醚的多相催化剂及工艺的最新进展，特别强调了热力学和催化剂设计考量。在介绍了开发此类工艺的主要动机之后，我们首先总结了CO捕集以及绿色制氢路线的最重要方面。一旦引入了原料方面的情况，我们便仔细总结了用于这些重要加氢反应的多相催化剂的开发现状。最后，为了对CO的价值评估给出一个大致的量级，我们批判性地评估了甲醇和二甲醚生产的经济方面，并概述了未来的研发方向。
