Mechanical Engineering, University of Alberta, Edmonton, AB, T6G 1H9, Canada.
School of Public Health, University of Michigan, 1420 Washington Heights, Ann Arbor, MI, 48109, USA.
Int Arch Occup Environ Health. 2019 Jan;92(1):141-153. doi: 10.1007/s00420-018-1353-0. Epub 2018 Oct 1.
Exposures of nail salon technicians have received attention due to the potentially toxic materials used in nail products, which include volatile organic compounds (VOCs) such as formaldehyde and methyl methacrylate (MMA). This study characterized area and personal concentrations and other indoor air parameters in 17 nail salons in fall and winter seasons in three areas of Michigan.
VOC samples were analyzed using thermal desorption, gas chromatography and mass spectroscopy, and the VOC composition of 35 nail products (e.g., polish, top coat, base coat) was measured using headspace sampling. Ventilation rates were derived using CO concentrations, occupancy and building information, and VOC sources were apportioned by a novel application of chemical mass balance models.
We detected ethyl acetate, propyl acetate, butyl acetate, MMA, n-heptane and toluene in most salons, and benzene, D-limonene, formaldehyde, and ethyl methacrylate in some salons. While MMA was not measured in the consumer and professional products, and the use of pure MMA in salons has been not been permitted since the 1970s, MMA was found in air at concentrations from 100 to 36,000 µg/m in 15 of 17 salons; thus its use appears to be commonplace in the industry. Personal measurements, representing exposures to workers and clients, were about twice those of the area measurements for many VOCs.
This study identifies the products responsible for emissions, shows the widespread presence of MMA, and documents low ventilation rates in some salons. It also demonstrates that "informal" short-term sampling approaches can evaluate chemical exposures in nail salons, providing measurements that can be used to protect a potentially susceptible and vulnerable population. Additional controls, including restrictions on the VOC compositions and improved ventilation, can reduce exposures to salon workers and clients.
由于指甲产品中使用了潜在有毒物质,指甲沙龙技师的暴露问题引起了关注,这些物质包括挥发性有机化合物(VOC),如甲醛和甲基丙烯酸甲酯(MMA)。本研究在密歇根州三个地区的秋季和冬季,对 17 家美甲沙龙的区域和个人浓度以及其他室内空气参数进行了特征描述。
使用热解吸、气相色谱和质谱法分析 VOC 样品,使用顶空采样法测量 35 种指甲产品(如指甲油、顶涂层、底涂层)的 VOC 成分。通风率是根据 CO 浓度、占用率和建筑物信息推导出的,VOC 源是通过化学质量平衡模型的新应用进行分配的。
我们在大多数沙龙中检测到乙酸乙酯、乙酸丙酯、乙酸丁酯、MMA、正庚烷和甲苯,在一些沙龙中检测到苯、D-柠檬烯、甲醛和甲基丙烯酸乙酯。虽然 MMA 没有在消费者和专业产品中测量,而且自 20 世纪 70 年代以来,沙龙中就不允许使用纯 MMA,但我们在 17 家沙龙中的 15 家沙龙空气中发现了浓度在 100 到 36000μg/m 的 MMA;因此,它在该行业的使用似乎很普遍。代表工人和客户暴露的个人测量值,对于许多 VOC 来说,大约是区域测量值的两倍。
本研究确定了排放的责任产品,显示了 MMA 的广泛存在,并记录了一些沙龙中通风率较低的情况。它还表明,“非正式”的短期采样方法可以评估指甲沙龙中的化学暴露情况,提供可用于保护潜在易受影响和脆弱人群的测量值。包括限制 VOC 成分和改善通风在内的其他控制措施,可以减少沙龙工人和客户的暴露。