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中国合肥不同功能区室内灰尘中重金属的特征及健康风险评估。

Characteristics and health risk assessment of heavy metals in indoor dust from different functional areas in Hefei, China.

机构信息

CAS Key Laboratory of Crust-Mantle Materials and Environment, School of Earth and Space Sciences, University of Science and Technology of China, Hefei, Anhui, 230026, China; State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, The Chinese Academy of Sciences, Xi'an, Shaanxi, 710075, China.

CAS Key Laboratory of Crust-Mantle Materials and Environment, School of Earth and Space Sciences, University of Science and Technology of China, Hefei, Anhui, 230026, China; State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, The Chinese Academy of Sciences, Xi'an, Shaanxi, 710075, China.

出版信息

Environ Pollut. 2019 Aug;251:839-849. doi: 10.1016/j.envpol.2019.05.058. Epub 2019 May 16.

Abstract

Metals in indoor dust pose potential health risks to humans. Dust deposition on air conditioner filters can represent the resuspended particulate matter in indoor air. However, few studies have examined this until now. This study investigated the total concentrations and different chemical fractionations of Cd, Cr, Mn, Ni, Pb, Sb, V, and Zn in indoor dust from three different functional zones (the Chief District, Commercial District (CmD), and Industrial District) in Hefei. The mean metal concentrations in indoor dust decreased in the following order: Zn > Mn > Pb > Cr > Ni > V > Cd > Sb. Cd, Pb, and Zn mainly existed in the mobile fraction. Cr and V mainly existed in the residual fraction. The enrichment factor and geo-accumulation index values of heavy metals were all ranked in the order of Cd > Zn > Pb > Sb > Ni > Cr > V, and these values in indoor dust were larger than those in outdoor dust. In addition, the enrichment patterns of these elements were similar in the three functional areas. The orders of non-carcinogenic risk (hazard index; HI) for the different functional areas for children were roughly the same, but there were clear differences for adults. In general, all the HIs were less than 1, which were within the internationally recognized safe range. The total carcinogenic risk (TR) was in the order of Cr > Pb > Cd for both children and adults in the three functional zones. The TRs from Cr exposure were not negligible. The TRs were significantly higher in the CmD.

摘要

室内灰尘中的金属对人类健康构成潜在风险。空调过滤器上的灰尘沉积可以代表室内空气中再悬浮的颗粒物。然而,直到现在,很少有研究对此进行过调查。本研究调查了合肥三个不同功能区(主城区、商业区(CmD)和工业区)室内灰尘中 Cd、Cr、Mn、Ni、Pb、Sb、V 和 Zn 的总浓度和不同化学形态。室内灰尘中金属的平均浓度按以下顺序降低:Zn > Mn > Pb > Cr > Ni > V > Cd > Sb。Cd、Pb 和 Zn 主要存在于可移动部分。Cr 和 V 主要存在于残留部分。重金属的富集因子和地积累指数值均按 Cd > Zn > Pb > Sb > Ni > Cr > V 的顺序排列,且室内灰尘中的这些值大于室外灰尘中的值。此外,这些元素在三个功能区的富集模式相似。不同功能区儿童的非致癌风险(危害指数;HI)顺序大致相同,但成人的 HI 则存在明显差异。总体而言,所有 HI 均小于 1,处于国际公认的安全范围内。对于三个功能区的儿童和成人,总致癌风险(TR)的顺序均为 Cr > Pb > Cd。Cr 暴露的 TR 不容忽视。在 CmD,TR 明显更高。

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