Chemical Constituents from and Their Antifungal and Herbicidal Activities.

The phytochemical investigation of led to the isolation and characterization of ten compounds which were identified as fraxin (), fraxetin (), esculetin (), cichoriin (), euphorbetin (), kaempferol-3---rutinoside (), oleuropein (), linoleic acid (), methyl linoleate (), and -sitosterol (). Structures of the isolated constituents were characterized by H NMR, C NMR and HRMS. All the compounds, except compounds and were isolated for the first time from this plant. Further, this was the first report for the occurrence of compound in the species. Antifungal activity evaluation showed that compound exhibited significant inhibitory effects against and with EC values of 0.31 ± 0.01 mmol/L, 10.50 ± 0.02 mmol/L, and 0.40 ± 0.02 mmol/L respectively, compared to the positive control, Carbendazim, with its EC values of 0.74 ± 0.01 mmol/L, 1.78 ± 0.01 mmol/L and 1.41 ± 0.00 mmol/L. Herbicidal activity tests showed that compounds - had strong inhibitory effects against the roots of with EC values of 1.16 ± 0.23 mmol/L, 1.28 ± 0.58 mmol/L and 1.33 ± 0.35 mmol/L respectively, more potently active than that of the positive control, Cyanazine, with its EC values of 1.56 ± 0.44 mmol/L. However, none of the compounds proved to be active against the tested bacteria ( and ).