Center for Nanochemistry, Beijing Science and Engineering Center for Nanocarbons, Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking University, Beijing, China.
Center for Multidimensional Carbon Materials, Institute for Basic Science, Ulsan, South Korea.
Nature. 2023 Apr;616(7955):66-72. doi: 10.1038/s41586-023-05797-z. Epub 2023 Mar 22.
Precise integration of two-dimensional (2D) semiconductors and high-dielectric-constant (k) gate oxides into three-dimensional (3D) vertical-architecture arrays holds promise for developing ultrascaled transistors, but has proved challenging. Here we report the epitaxial synthesis of vertically aligned arrays of 2D fin-oxide heterostructures, a new class of 3D architecture in which high-mobility 2D semiconductor fin BiOSe and single-crystal high-k gate oxide BiSeO are epitaxially integrated. These 2D fin-oxide epitaxial heterostructures have atomically flat interfaces and ultrathin fin thickness down to one unit cell (1.2 nm), achieving wafer-scale, site-specific and high-density growth of mono-oriented arrays. The as-fabricated 2D fin field-effect transistors (FinFETs) based on BiOSe/BiSeO epitaxial heterostructures exhibit high electron mobility (μ) up to 270 cm V s, ultralow off-state current (I) down to about 1 pA μm, high on/off current ratios (I/I) up to 10 and high on-state current (I) up to 830 μA μm at 400-nm channel length, which meet the low-power specifications projected by the International Roadmap for Devices and Systems (IRDS). The 2D fin-oxide epitaxial heterostructures open up new avenues for the further extension of Moore's law.
二维(2D)半导体和高介电常数(k)栅氧化物的精确集成到三维(3D)垂直架构阵列有望开发出超小型晶体管,但事实证明这具有挑战性。在这里,我们报告了二维(2D)Fin-氧化物异质结构的垂直对准阵列的外延合成,这是一种新的 3D 架构,其中高迁移率的 2D 半导体 Fin BiOSe 和单晶高 k 栅氧化物 BiSeO 被外延集成。这些 2D Fin-氧化物外延异质结构具有原子级平坦的界面和超薄的 Fin 厚度,低至一个单元(1.2nm),实现了晶圆级、特定位置和高密度的单取向阵列生长。基于 BiOSe/BiSeO 外延异质结构的制造的 2D FinFET 表现出高达 270cmV/s 的高电子迁移率(μ)、低至约 1pA/μm 的超低关态电流(I)、高达 10 的高开关电流比(I/I)和高达 830μA/μm 的高导通电流(I)在 400nm 沟道长度下,这满足了国际器件和系统路线图(IRDS)预测的低功耗规格。2D Fin-氧化物外延异质结构为进一步扩展摩尔定律开辟了新途径。