Department of Geology, United Arab Emirates University, Al-Ain 15551, United Arab Emirates.
Department of Physics, United Arab Emirates University, Al-Ain 15551, United Arab Emirates.
Molecules. 2021 Feb 4;26(4):796. doi: 10.3390/molecules26040796.
Magnetite (FeO) nanoparticles were synthesized using the chemical coprecipitation method. Several nanoparticle samples were synthesized by varying the concentration of iron salt precursors in the solution for the synthesis. Two batches of nanoparticles with average sizes of 10.2 nm and 12.2 nm with nearly similar particle-size distributions were investigated. The average particle sizes were determined from the XRD patterns and TEM images. For each batch, several samples with different particle concentrations were prepared. Morphological analysis of the samples was performed using TEM. The phase and structure of the particles of each batch were studied using XRD, selected area electron diffraction (SAED), Raman and XPS spectroscopy. Magnetic hysteresis loops were obtained using a Lakeshore vibrating sample magnetometer (VSM) at room temperature. In the two batches, the particles were found to be of the same pure crystalline phase of magnetite. The effects of particle size, size distribution, and concentration on the magnetic properties and magneto thermic efficiency were investigated. Heating profiles, under an alternating magnetic field, were obtained for the two batches of nanoparticles with frequencies 765.85, 634.45, 491.10, 390.25, 349.20, 306.65, and 166.00 kHz and field amplitudes of 100, 200, 250, 300 and 350 G. The specific absorption rate (SAR) values for the particles of size 12.2 nm are higher than those for the particles of size 10.2 nm at all concentrations and field parameters. SAR decreases with the increase of particle concentration. SAR obtained for all the particle concentrations of the two batches increases almost linearly with the field frequency (at fixed field strength) and nonlinearly with the field amplitude (at fixed field frequency). SAR value obtained for magnetite nanoparticles with the highest magnetization is 145.84 W/g at 765.85 kHz and 350 G, whereas the SAR value of the particles with the least magnetization is 81.67 W/g at the same field and frequency.
采用化学共沉淀法合成了磁铁矿(FeO)纳米粒子。通过改变溶液中铁盐前体的浓度,合成了多个纳米粒子样品。研究了两个平均粒径分别为 10.2nm 和 12.2nm、粒径分布相近的纳米粒子批次。平均粒径由 XRD 图谱和 TEM 图像确定。对于每个批次,都制备了具有不同颗粒浓度的多个样品。使用 TEM 对样品进行了形态分析。使用 XRD、选区电子衍射(SAED)、拉曼和 XPS 光谱研究了每个批次的颗粒的相和结构。使用 Lakeshore 振动样品磁强计(VSM)在室温下获得磁滞回线。在这两个批次中,发现颗粒均为相同的纯磁铁矿晶相。研究了粒径、粒径分布和浓度对磁性和磁热效率的影响。获得了两个批次的纳米粒子在频率为 765.85、634.45、491.10、390.25、349.20、306.65 和 166.00kHz 以及磁场强度为 100、200、250、300 和 350G 的交变磁场下的加热曲线。粒径为 12.2nm 的粒子的比吸收率(SAR)值在所有浓度和场参数下均高于粒径为 10.2nm 的粒子。SAR 随颗粒浓度的增加而降低。两个批次的所有颗粒浓度的 SAR 值随磁场频率(在固定磁场强度下)几乎呈线性增加,随磁场幅度(在固定磁场频率下)呈非线性增加。在 765.85kHz 和 350G 下,具有最高磁化强度的磁铁矿纳米粒子的 SAR 值为 145.84W/g,而具有最小磁化强度的粒子的 SAR 值为 81.67W/g,在相同的磁场和频率下。
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