National Center for Nanoscience and Technology, Zhongguancun, Beijing, 100190, P. R. China.
State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing, 100084, P. R. China.
Small. 2016 Feb 3;12(5):595-601. doi: 10.1002/smll.201502336. Epub 2015 Dec 8.
A graphene/n-type silicon (n-Si) heterojunction has been demonstrated to exhibit strong rectifying behavior and high photoresponsivity, which can be utilized for the development of high-performance photodetectors. However, graphene/n-Si heterojunction photodetectors reported previously suffer from relatively low specific detectivity due to large dark current. Here, by introducing a thin interfacial oxide layer, the dark current of graphene/n-Si heterojunction has been reduced by two orders of magnitude at zero bias. At room temperature, the graphene/n-Si photodetector with interfacial oxide exhibits a specific detectivity up to 5.77 × 10(13) cm Hz(1/2) W(-1) at the peak wavelength of 890 nm in vacuum, which is highest reported detectivity at room temperature for planar graphene/Si heterojunction photodetectors. In addition, the improved graphene/n-Si heterojunction photodetectors possess high responsivity of 0.73 A W(-1) and high photo-to-dark current ratio of ≈10(7) . The current noise spectral density of the graphene/n-Si photodetector has been characterized under ambient and vacuum conditions, which shows that the dark current can be further suppressed in vacuum. These results demonstrate that graphene/Si heterojunction with interfacial oxide is promising for the development of high detectivity photodetectors.
已证实,石墨烯/n-型硅(n-Si)异质结具有很强的整流性能和高光敏性,可用于开发高性能光电探测器。然而,之前报道的石墨烯/n-Si 异质结光电探测器由于暗电流较大,其特定探测率相对较低。在这里,通过引入薄的界面氧化层,在零偏压下,石墨烯/n-Si 异质结的暗电流降低了两个数量级。在室温下,具有界面氧化层的石墨烯/n-Si 光电探测器在真空中的峰值波长为 890nm 时,其特定探测率高达 5.77×10(13) cm Hz(1/2) W(-1),这是室温下平面石墨烯/Si 异质结光电探测器的最高报道探测率。此外,改进后的石墨烯/n-Si 异质结光电探测器具有 0.73A W(-1)的高响应率和 ≈10(7)的高光电流暗电流比。在环境和真空条件下对石墨烯/n-Si 光电探测器的电流噪声谱密度进行了表征,结果表明在真空中可以进一步抑制暗电流。这些结果表明,具有界面氧化层的石墨烯/Si 异质结有望开发出高探测率的光电探测器。