Beijing National Laboratory for Condensed Matter Physics and Institute of Physics, Chinese Academy of Sciences, Beijing, 100190, China.
School of Physical Sciences, University of Chinese Academy of Sciences, Beijing, 100190, China.
Nat Commun. 2023 Jun 19;14(1):3633. doi: 10.1038/s41467-023-39390-9.
Monolayer molybdenum disulfide (ML-MoS) is an emergent two-dimensional (2D) semiconductor holding potential for flexible integrated circuits (ICs). The most important demands for the application of such ML-MoS ICs are low power consumption and high performance. However, these are currently challenging to satisfy due to limitations in the material quality and device fabrication technology. In this work, we develop an ultra-thin high-κ dielectric/metal gate fabrication technique for the realization of thin film transistors based on high-quality wafer scale ML-MoS on both rigid and flexible substrates. The rigid devices can be operated in the deep-subthreshold regime with low power consumption and show negligible hysteresis, sharp subthreshold slope, high current density, and ultra-low leakage currents. Moreover, we realize fully functional large-scale flexible ICs operating at voltages below 1 V. Our process could represent a key step towards using energy-efficient flexible ML-MoS ICs in portable, wearable, and implantable electronics.
单层二硫化钼 (ML-MoS) 是一种新兴的二维 (2D) 半导体,具有用于柔性集成电路 (IC) 的潜力。对于此类 ML-MoS IC 的应用,最重要的要求是低功耗和高性能。然而,由于材料质量和器件制造技术的限制,目前很难满足这些要求。在这项工作中,我们开发了一种超薄高介电常数/金属栅极制造技术,用于在刚性和柔性衬底上实现基于高质量晶圆级 ML-MoS 的薄膜晶体管。刚性器件可以在深亚阈值区工作,具有低功耗和可忽略的迟滞现象、陡峭的亚阈值斜率、高电流密度和超低漏电流。此外,我们实现了全功能的大规模柔性 IC,工作电压低于 1V。我们的工艺可能是在可移植、可穿戴和可植入电子设备中使用节能型柔性 ML-MoS IC 的关键步骤。